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Battery Claims Greater Capacity than Lithium-ion
Oxis Energy in Oxfordshire, U.K., is developing
a rechargeable battery with more capacity than
lithium-ion.
It has a high gravimetric density, twice
the energy density per unit weight of Li-ion,
and not just on the first charge-discharge cycle,
said director Dr. Matthew Frohn. Cycle life
is certainly in excess of 300 cycles, he
added.
The chemistry inside is a form of lithium-sulphur.
There are a number of interesting approaches
in Li-S chemistry, said Frohn. However,
there are some intrinsic problems.
These include a high level of self-discharge and
low cycle life through dendrite growth. Through
undisclosed modifications to Li-S cell chemistry
and structure, Oxis has invented what it dubs
a lithium-sulphide cell.
It is a significant improvement over lithium
sulphur, said chief technologist Dr. Gleb
Ivanov.
The cell has a metallic lithium anode, something
which has caused nervousness in the past following
spontaneous combustion with now defunct rechargeable
lithium cells over a decade ago. Li-ion and Li-polymer
cells have no metallic lithium and only form it
when they are abused.
Our cell electro-chemistry is a combination
of lithium and poly-sulphur and is extremely safe.
It has an intrinsically safe mechanism; the lithium
metal is effectively passivated, said Ivanov.
We have done nail penetration, over-charge
and short-circuit tests and all tests were positive,
he said.
Ivanov claims another advantage: You can
draw 2C or 4C, he said, and we rate
our capacity at C/2. Li-ion cells are rated at
C/4 discharge.
The cells can deliver higher power levels than
most Li-ion cells, and their capacities are rated
conservatively.
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